2023 No. 2
Article Contents

LI Jun, YANG Guoli, ZHU Xiuqun, XU Li, ZHU Danni, ZHAO Yi, LI Yanqing, LAN Funing. Water quality analysis and evaluation of irrigation applicability in Nandong underground river basin, Southwest China[J]. Carsologica Sinica, 2023, 42(2): 207-219. doi: 10.11932/karst20230203
Citation: LI Jun, YANG Guoli, ZHU Xiuqun, XU Li, ZHU Danni, ZHAO Yi, LI Yanqing, LAN Funing. Water quality analysis and evaluation of irrigation applicability in Nandong underground river basin, Southwest China[J]. Carsologica Sinica, 2023, 42(2): 207-219. doi: 10.11932/karst20230203

Water quality analysis and evaluation of irrigation applicability in Nandong underground river basin, Southwest China

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  • The karst surface water and groundwater of Nandong underground river basin are vital water sources for agricultural and industrial production, and lives of residents in Honghe Hani and Yi Autonomous Prefecture in Yunnan, Southwest China. With a growing public awareness of water environment and water safety, the evaluation of karst water quality and irrigation applicability especially in agricultural regions is becoming increasingly necessary. In this study, 32 samples of karst surface river water and 24 samples of underground river water were collected from Nandong underground river basin during dry and rainy seasons. 11 inorganic regular ions (i.e., K+, Na+, Ca2+, Mg2+, Cl, < span class="inline-formula-span" > ${\rm{SO}}_4^{2-}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015121.png'/ > , < span class="inline-formula-span" > < span class="inline-formula-span" > ${\rm{HCO}}_3^{-}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015126.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015122.png'/ > , < span class="inline-formula-span" > ${\rm{NO}}_3^{-}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015123.png'/ > , NO < span class="inline-formula-span" > $_2^{−}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015124.png'/ > , NH < span class="inline-formula-span" > < span class="inline-formula-span" > < span class="inline-formula-span" > $_4^{+}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015128.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015127.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015125.png'/ > , and F) and 9 heavy metals (i.e., Al, Cu, Pb, Zn, Cr, Cd, Ni, Mn, and As) were analyzed in these samples to investigate the water quality and irrigation applicability. Based on the measured concentrations of the hydrochemical composition, the Nemerow composite index in combination with the four irrigation assessment systems of sodium concentration (SC), sodium adsorption ratio (SAR), residual sodium carbonate (RSC), and permeability index (PI) were applied to evaluate the karst water quality and irrigation applicability, respectively. Results show that Ca2+ and < span class="inline-formula-span" > < span class="inline-formula-span" > ${\rm{HCO}}_3^{-}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015126.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015122.png'/ > were identified as the major ions in both karst surface water and karst groundwater, indicating weakly alkaline karst water in the study area. For karst surface water, among the 11 inorganic regular ions, only NH < span class="inline-formula-span" > < span class="inline-formula-span" > < span class="inline-formula-span" > $_4^{+}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015128.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015127.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015125.png'/ > was found exceeding the maximum acceptable level for drinking water recommended by General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China. Meanwhile, among the 9 heavy metals, the concentrations of Al, Pb, Mn, and As were evaluated as exceeding the maximum acceptable level. Moreover, the rates of measured ions exceeding permitted levels in the dry season were generally higher than those in the rainy season. For karst groundwater, the concentrations of Al, Pb, Zn, Cr, Mn, and As exceeded the maximum acceptable levels, and the rates of these metals exceeding permitted levels in the rainy season were generally higher than those in dry season. The nitrogen synthetic fertilizers might be a main cause of the increase of NH < span class="inline-formula-span" > < span class="inline-formula-span" > < span class="inline-formula-span" > $_4^{+}$ < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015128.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015127.png'/ > < /span > < img text_id='' class='formula-img' style='display:none;' src='lijun_M015125.png'/ > concentration in karst surface water. High concentration of Al, Mn, and Cd in karst water were mainly caused by large amounts of discharge from metal smelting, waste residue of mining, and open-pit mining. Furthermore, an exposed surface environment of bedrock in some parts of this study area might be responsible for these components exceeding the permitted levels due to the lack of surface decontamination of pollutants. The karst water quality belonging to the good grade or above accounted for 89.29% and 85.71% of the total water samples collected during the dry season and the rainy season, respectively, and the quality belonging to poor grade or below accounted for 7.14% and 14.29%, respectively. Hence, the karst water quality in Nandong underground river basin was generally high based on the results of the assessment of karst water quality. However, some cases of poor-quality karst water were found in parts of our study area (e.g., G1 and S4 sampling sites in the dry season and G1, G2, and G3 sampling sites in the rainy season), accompanied by the seasonal differences in karst water pollution. According to the permitted level for irrigation water and the results of SC, SAR, RSC, and PI assessments, most of the karst water in Nandong underground river basin was generally suitable for irrigation. However, it is noted that the concentration of As (54.70 μg·L−1) in the sampling site of surface water (i.e., S3) exceeded the permitted level for the irrigation of vegetables and water crops in the dry season, thereby being no longer suitable for irrigation. Our results suggest that the high concentrations of metal compositions (e.g., Al, Pb, Mn, and As) should be controlled by some targeted measures to prevent further metal pollution in karst water of Nandong underground river basin. Our study also provides an integrated method for the comprehensive understanding of water quality in karst surface water and groundwater.

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  • [1] Jiang Y, Wu Y, Groves C, Yuan D, Kambesis P. Natural and anthropogenic factors affecting the groundwater quality in the Nandong karst underground river system in Yunan, China[J]. Journal of Contaminant Hydrology, 2009, 109:49-61. doi: 10.1016/j.jconhyd.2009.08.001

    CrossRef Google Scholar

    [2] 袁道先, 蔡桂鸿. 岩溶环境学[M]. 重庆: 重庆出版社, 1988, 20-30.

    Google Scholar

    YUAN Daoxian, CAI Guihong. Karst Environmentology[M]. Chongqing: Chongqing Publishing House, 1988, 20-30.

    Google Scholar

    [3] 朱秀群. 南洞岩溶水系统水文地球化学特征及形成机制研究[D]. 北京: 中国地质大学(北京), 2020.

    Google Scholar

    ZHU Xiuqun. Study on hydrogeochemistry characteristics and formation mechanism in Nandong karst water system[D]. Beijing: China University of Geosciences, 2020.

    Google Scholar

    [4] 李军, 邹胜章, 梁永平, 林永生, 周长松, 赵一. 会仙岩溶湿地水体金属元素分布与健康风险评价[J]. 环境科学, 2020, 41(11):4948-4957. doi: 10.13227/j.hjkx.202003212

    CrossRef Google Scholar

    LI Jun, ZOU Shengzhang, LIANG Yongping, LIN Yongsheng, ZHOU Changsong, ZHAO Yi. Metal distributions and human health risk assessments on waters in Huixian karst wetland, China[J]. Environmental Science, 2020, 41(11):4948-4957. doi: 10.13227/j.hjkx.202003212

    CrossRef Google Scholar

    [5] Kohl D H, Shearer B G, Commoner B. Fertiliter nitrogen: Contribution to nitrate in surface water in a Corn Belt Watershed[J]. Science, 1971, 174: 1331-1334.

    Google Scholar

    [6] Nestler A, Berglund M, Accoe F, Duta S, Xue D, Boeckx P, Taylor P. Isotopes for improved management of nitrate pollution in aqueous resources: Review of surface water field studies[J]. Environmental Science and Pollution Research, 2011, 18: 519-533.

    Google Scholar

    [7] Burkart M R, Kolpin D W. Hydrologic and land-use factors associated with herbicides and nitrate in near-surface aquifers[J]. Journal of Environmental Quality, 1993, 22(4):646-656.

    Google Scholar

    [8] MIAO Xiongyi, HAO Yupei, ZHANG Fawang, ZOU Shengzhang, YE Siyuan, XIE Zhouqing. Spatial distribution of heavy metals and their potential sources in the soil of Yellow River Delta: A traditional oil field in China[J]. Environmental Geochemistry and Health, 2019, 42(1):7-26.

    Google Scholar

    [9] LI Jun, MIAO Xiongyi, HAO Yupei, XIE Zhouqing, ZOU Shengzheng, ZHOU Changsong. Health risk assessment of metals (Cu, Pb, Zn, Cr, Cd, As, Hg, Se) in angling fish with different lengths collected from Liuzhou, China[J]. International Journal of Environmental Research Public Health, 2020, 17, 2192.

    Google Scholar

    [10] ZHAO Xuemin, YAO Lingai, Ma Qianli, ZHOU Guangjie, XU Zhencheng. Distribution and ecological risk assessment of cadmium in water and sediment in Longjiang River, China: Implication on water quality management after pollution accident[J]. Chemosphere, 2017, 194:107.

    Google Scholar

    [11] Parise M, Waele J D, Gutierrez F. Current perspectives on the environmental impacts and hazards in karst[J]. Environmental Geology, 2009, 58(2):235-237. doi: 10.1007/s00254-008-1608-2

    CrossRef Google Scholar

    [12] Jiang Zhongcheng, Lian Yanqing, Qin Xiaojun. Rocky desertification in Southwest China: Impacts, causes, and restoration[J]. Earth-Science Reviews, 2014, 132(3):1-12.

    Google Scholar

    [13] Jiang Yongjun, Yan Jun. Effects of land use on hydrochemistry and contamination of karst groundwater from Nandong underground river system, China[J]. Water, Air, and Soil Pollution, 2010, 210:123-141.

    Google Scholar

    [14] Li Y Q, Jiang Z C, Chen Z H, Yu Y, Lan F, Shan Z J, Sun Y J, Liu P, Tang X B, Rodrigo-Comino J. Anthropogenic disturbances and precipitation affect karst sediment discharge in the Nandong Underground River System in Yunnan, Southwest China[J]. Sustainability, 2020, 12:3006. doi: 10.3390/su12073006

    CrossRef Google Scholar

    [15] 莫美仙, 王宇, 李峰, 虞慧. 云南南洞地下河系统边界及性质研究[J]. 中国岩溶, 2019, 38(2):173-185.

    Google Scholar

    MO Meixian, WANG Yu, LI Feng, YU Hui. Study on the boundaries and properties of the underground river system in Nandong, Yunnan Province[J]. Carsologica Sinica, 2019, 38(2):173-185.

    Google Scholar

    [16] 伍鹏, 舒倩, 罗小芳, 伍钢. 湘西古丈烂泥田锰矿区地表水污染特征及风险评价[J]. 水土保持通报, 2019, 39(3):70-74. doi: 10.13961/j.cnki.stbctb.2019.03.012

    CrossRef Google Scholar

    WU Peng, SHU Qian, LUO Xiaofang, WU Gang. Surface water pollution and risk assessment at a manganese mining area located in mud field in Guzhang county of western Hu'nan Province[J]. Bulletin of Soil and Water Conservation, 2019, 39(3):70-74. doi: 10.13961/j.cnki.stbctb.2019.03.012

    CrossRef Google Scholar

    [17] 周巾枚, 蒋忠诚, 徐光黎, 覃小群, 黄奇波, 张连凯. 崇左响水地区地下水水质分析及健康风险评价[J]. 环境科学, 2019, 40(6):2675-2685.

    Google Scholar

    ZHOU Jinmei, JIANG Zhongcheng, XU Guangli, QIN Xiaoqun, HUANG Qibo, ZHANG Liankai. Water quality analysis and health risk assessment for groundwater at Xiangshui, Chongzuo[J]. Environmental Science, 2019, 40(6):2675-2685.

    Google Scholar

    [18] 国家环境保护总局. GB 3838—2002 地表水环境质量标准[S].

    Google Scholar

    State Bureau of Environmental Protection. GB 3838—2002 Environmental quality standards for surface water[S].

    Google Scholar

    [19] 国家技术监督局. GB/T14848—2017 地下水质量标准[S].

    Google Scholar

    The State Bureau of Quality and Technical Supervision. GB/T14848—2017 Quality standard for ground water[S].

    Google Scholar

    [20] 中华人民共和国卫生部. GB5749—2006 生活饮用水卫生标准[S].

    Google Scholar

    Ministy of Health P. R. China. GB5749—2006 Standard of drinking water quality[S].

    Google Scholar

    [21] 毛萌, 朱雪芹. 宣化盆地地下水化学特性及灌溉适用性评价[J]. 干旱区资源与环境, 2020, 34(7):142-149. doi: 10.13448/j.cnki.jalre.2020.195

    CrossRef Google Scholar

    MAO Meng, ZHU Xueqin. Chemical characteristics of groundwater in Xuanhua basin and assessment of irrigation applicability[J]. Journal of Arid Land Resources and Environment, 2020, 34(7):142-149. doi: 10.13448/j.cnki.jalre.2020.195

    CrossRef Google Scholar

    [22] Sen Z. Practical and Applied Hydrogeology[M]. Elsevier, 2015.

    Google Scholar

    [23] 朱丹尼, 邹胜章, 李军, 樊连杰, 赵一, 谢浩, 朱天龙, 潘民强, 徐利. 会仙岩溶湿地丰平枯水期地表水污染及灌溉适用性评价[J]. 环境科学, 2021, 42(5):2240-2250.

    Google Scholar

    ZHU Danni, ZOU Shengzhang, LI Jun, FAN Lianjie, ZHAO Yi, XIE Hao, ZHU Tianlong, PAN Minqiang, XU Li. Pollution and irrigation applicability on surface water from wet, normal, and dry periods in Huixian karst wetland, China[J]. Environmental Science, 2021, 42(5):2240-2250.

    Google Scholar

    [24] 张恒星, 张翼龙, 李政红, 王文中, 郝奇琛. 基于主导离子分类的呼和浩特盆地浅层地下水化学特征研究[J]. 干旱区资源与环境, 2019, 33(4):189-195.

    Google Scholar

    ZHANG Hengxing, ZHANG Yilong, LI Zhenghong, WANG Wenzhong, HAO Qichen. Chemical characteristics of shallow groundwater in Hohhot basin[J]. Journal of Arid Land Resources and Environment, 2019, 33(4):189-195.

    Google Scholar

    [25] 王波, 王宇, 张贵, 张华, 代旭升, 康晓波. 滇东南泸江流域岩溶地下水质量及污染影响因素研究[J]. 地球学报, 2021, 42(3):352-362.

    Google Scholar

    WANG Bo, WANG Yu, ZHANG Gui, ZHANG Hua, DAI Xusheng, KANG Xiaobo. A study of quality and pollution factors of karst groundwater in Lujiang river basin in southeast Yunnan[J]. Acta Geoscientica Sinica, 2021, 42(3):352-362.

    Google Scholar

    [26] 李军, 邹胜章, 赵一, 赵瑞科, 党志文, 潘民强, 朱丹尼, 周长松. 会仙岩溶湿地地下水主要离子特征及成因分析[J]. 环境科学, 2021, 42(4):1750-1760.

    Google Scholar

    LI Jun, ZOU Shengzhang, ZHAO Yi, ZHAO Ruike, DANG Zhiwen, PAN Minqiang, ZHU Danni, ZHOU Changsong. Major ionic characteristics and factors of karst groundwater at Huixian karst wetland, China[J]. Environmental Science, 2021, 42(4):1750-1760.

    Google Scholar

    [27] 周巾枚, 蒋忠诚, 徐光黎, 覃小群, 黄奇波, 张连凯. 崇左响水地区岩溶地下水主要离子特征及控制因素[J]. 环境科学, 2019, 40(5):2143-2151. doi: 10.13227/j.hjkx.201810021

    CrossRef Google Scholar

    ZHOU Jinmei, JIANG Zhongcheng, XU Guangli, QIN Xiaoqun, HUANG Qibo, ZHANG Liankai. Major ionic characteristics and controlling factors of karst groundwater at Xiangshui, Chongzuo[J]. Environmental Science, 2019, 40(5):2143-2151. doi: 10.13227/j.hjkx.201810021

    CrossRef Google Scholar

    [28] 魏兴, 周金龙, 乃尉华, 曾妍妍, 范薇, 李斌. 新疆喀什三角洲地下水SO42−化学特征及来源[J]. 环境科学, 2019(8):3550-3558.

    Google Scholar

    WEI Xing, ZHOU Jinlong, NAI Weihua, ZENG Yanyan, FAN Wei, LI Bin. Chemical characteristics and sources of groundwater sulfate in the Kashgar Delta, Xinjiang[J]. Environmental Science, 2019(8):3550-3558.

    Google Scholar

    [29] Delpla I, Jung A V, Bauers E, Clement M, Thomas O. Impact of climate change on surface water quality in relation to drinking water production[J]. Environment Internation, 2009, 35(8):1225-1233.

    Google Scholar

    [30] Nolan B T, Hitt K J. Vulnerability of shallow groundwater a drinking-water wells to nitrate in the United States[J]. Environmental Science and Technology, 2006, 40(24):7834-7840.

    Google Scholar

    [31] 张小文, 何江涛, 黄冠星. 石家庄地区浅层地下水铁锰分布特征及影响因素分析[J]. 地学前缘, 2020. doi: 10.13745/j.esf.sf.2020.7.4.

    Google Scholar

    ZHANG Xiaowen, HE Jiangtao, HUANG Guanxing. Distribution characteristics and cause analysis of iron and manganese in shallow groundwater in Shijiazhuang area[J]. Earth Science Frontiers, 2020. doi: 10.13745/j.esf.sf.2020.7.4.

    Google Scholar

    [32] 王宇. 西南岩溶地区岩溶水系统分类、特征及勘查评价要点[J]. 中国岩溶, 2002(2):44-49. doi: 10.3969/j.issn.1001-4810.2002.02.008

    CrossRef Google Scholar

    WANG Yu. Classification, features of karst water system and key point for the evaluation to karst water exploration in Southwest China karst area[J]. Carsologica Sinica, 2002(2):44-49. doi: 10.3969/j.issn.1001-4810.2002.02.008

    CrossRef Google Scholar

    [33] 刘全吉. 冬小麦、油菜对砷污染反应的比较研究[D]. 武汉: 华中农业大学, 2008.

    Google Scholar

    LIU Quanji. Comparision of responses of winter wheat (Triticum aestivum L.) and rape (Brassica napus) to arsenic stress pollution[D]. Wuhan: Huazhong Agricultural University, 2008.

    Google Scholar

    [34] 张秀武. 葫芦岛市锌厂周围砷污染格局与生态风险评价[D]. 北京: 中国科学院, 2008.

    Google Scholar

    ZHANG Xiuwu. Spatial pattern and risk assessment of soil arsenic around Huludao zinc plant[D]. Beijing: Chinese Academy of Sciences, 2008.

    Google Scholar

    [35] 国家环境保护局. GB 5084-2005 农田灌溉水质标准[S].

    Google Scholar

    State Bureau of Environmental Protection. GB 5084-2005 Standard for irrigation water quality[S].

    Google Scholar

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